A new phosphoric triamide with the formula [2-Cl-C6H4C(O)NH]P(O)[NHC6H4-4- CH3]2 has been investigated by spectroscopic methods and X-ray crystallography. This compound crystallizes in the monoclinic system, with P21/c space group. In this molecule, the P atom has a distorted tetrahedral environment. The N atoms bonded to P atom have mainly sp2 character. In the crystal, the molecules are aggregated through NCPÃÂ¢Ãâ¬Ãâ¢H…OÃÂ¢Ãâ¢ÃÂP and NPÃÂ¢Ãâ¬Ãâ¢H…OÃÂ¢Ãâ¢ÃÂC hydrogen bonds in a linear arrangement along the b axis, by forming a sequence of alternate R22 (8) and R22 (12) motifs (NCP is the nitrogen atom of C(O)NHP(O) segment and the NP stands the two other nitrogen atoms bonded to the P atom). Furthermore, CÃÂ¢Ãâ¬Ãâ¢H…O and CÃÂ¢Ãâ¬Ãâ¢H…Cl intermolecular interactions complete a 3D structure.
Pourayoubi M, Taherzadeh M, Dusek M and Kucerakova M