Reach Us +441414719275

Abstract

A H-bonded Chloranilate Chain with an Unprecedented Topology

New (PPh3Et)2(C6O4Cl2)·2H2O (1) compound has been synthetized and structurally characterized. This compound presents layers of cations and non coordinated [C6O4Cl4]2-anions alternating along thecdirection. The cationic layers contains isolated [PPh3Et]+ cations whereas in the anionic layers the chloranilate anions are connected forming chains along the a direction thanks to two H-bonds formed between the oxygen atoms of the chloranilate anions and two water molecules located between two anions. The topology of this H-bonded chain is unprecedented in any chloranilate compound. Compound 1 is the first characterized salt containing noncoordinated chloranilate anions with any phosphonium cation.


Author(s):

Samia Benmansour, Cristina Vallis-Garcia, Carlos J Gomez-Garcia



Abstract | Full-Text | PDF

Share this  Facebook  Twitter  LinkedIn  Google+
Flyer image

Abstracted/Indexed in

  • Index Copernicus
  • Directory of Research Journal Indexing (DRJI)
  • WorldCat
  • Geneva Foundation for Medical Education and Research